Enhancing Hydrogen Storage Capacity of Pd Nanoparticles by Sandwiching between Inorganic Nanosheets

نویسندگان

چکیده

H2 is regarded to play a crucial role in the transition from fossil fuel-based energy economy towards an environmentally friendly one. However, storage of still challenging, but palladium (Pd) based materials show exciting properties. Therefore, nanoparticulate Pd has been intensely studied for hydrogen past years. Here, we stabilize nanoparticles by intercalation between inorganic nanosheets hectorite (NaHec). Compared stabilized polymer polyvinylpyrrolidone (PVP), capacity was found be 86 % higher identical being intercalated nanosheets. We attribute this remarkably enhanced partial oxidation Pd, as evidenced X-ray photoelectron spectroscopy (XPS). The amount holes 4d band leads that can absorbed when compared PVP nanoparticles.

برای دانلود باید عضویت طلایی داشته باشید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Hydrogen storage in carbon nanotubes with Ni nanoparticles by electrochemical

In this paper, the electrochemical hydrogen storage in nanocomposite materials was studied. Multi-Walled Carbon Nanotubes (MWCNTs) electrode was prepared by mixing with special composite. The optimum ratio of MWCNTs was estimated 30-70% (w/w) in the composite material. MWCNTs were synthesized by Chemical vapor deposition (CVD). The nanocomposite was homogenized by microwave. Cyclic voltammetry ...

متن کامل

Hydrogen storage in carbon nanotubes with Ni nanoparticles by electrochemical

In this paper, the electrochemical hydrogen storage in nanocomposite materials was studied. Multi-Walled Carbon Nanotubes (MWCNTs) electrode was prepared by mixing with special composite. The optimum ratio of MWCNTs was estimated 30-70% (w/w) in the composite material. MWCNTs were synthesized by Chemical vapor deposition (CVD). The nanocomposite was homogenized by microwave. Cyclic voltammetry ...

متن کامل

control of the optical properties of nanoparticles by laser fields

در این پایان نامه، درهمتنیدگی بین یک سیستم نقطه کوانتومی دوگانه(مولکول نقطه کوانتومی) و میدان مورد مطالعه قرار گرفته است. از آنتروپی ون نیومن به عنوان ابزاری برای بررسی درهمتنیدگی بین اتم و میدان استفاده شده و تاثیر پارامترهای مختلف، نظیر تونل زنی(که توسط تغییر ولتاژ ایجاد می شود)، شدت میدان و نسبت دو گسیل خودبخودی بر رفتار درجه درهمتنیدگی سیستم بررسی شده اشت.با تغییر هر یک از این پارامترها، در...

15 صفحه اول

Enhancing Mechanical Strength of Inorganic Geopolymer by Using Phenol Resin

The effect of organic phenol on the compressive and flexural strength of a metakaolin based geopolymer is studied. It was found that 12 wt% phenol resins can increase the compressive and flexural strength by 30% and 65% respectively. In addition, the reinforcing effect of phenol resin is higher in Na-PS and Na-PSS type geopolymers rather than Na-PSDS. Two distinct endothermic peaks were detecte...

متن کامل

Theoretical Performance Evaluation of Inorganic (Non Pd-Based) Membranes for Hydrogen Separation

The aim of this work theoretical study is to theoretically investigate a inorganic membrane assisted purifcation process of an H2-rich stream derived from a conventional methanol steam reforming stage. In particular, a black-box model for multicomponent gas mixture purifcation is dev...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ژورنال

عنوان ژورنال: Zeitschrift für anorganische und allgemeine Chemie

سال: 2022

ISSN: ['0044-2313', '1521-3749']

DOI: https://doi.org/10.1002/zaac.202100370